Product ID:KRYLON HIGH HEAT RESISTANT PAINTS, 1618 BBQ & STOVE BLACK
MSDS Date:08/17/1998
FSC:8010
NIIN:00N081390
Status Code:A
MSDS Number: CKJSX

SHERWIN-WILLIAMS CO, KRYLON/SPRAYON INDUSTRIAL PRODUCTS

31500 SOLON ROAD
SOLON, OH 44139
US

Emergency Phone: 216-566-2956

Info Phone: 800-777-2956

Cage: 09800

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

PROPANE. (VAPOR PRESSURE 760.0 MM HG)

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACETONE. (VAPOR PRESSURE 180.0 MM HG)

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 750 PPM

ACGIH TLV: 750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE. (VAPOR PRESSURE 22.0 MM HG)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM (SKIN)

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1-BUTANOL. (VAPOR PRESSURE 5.5 MM HG)

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 50 PPM (SKIN)

ACGIH TLV: C 50 PPM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3 (AS DUST)

ACGIH TLV: 3.5 MG/M3 (AS DUST)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TO MINIMIZE EXPOSURE, FOLLOW
RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND PERSONAL
PROTECTIVE EQUIPMENT. ACUTE: EFFECTS OF OVEREXPOSURE: IRRITATION OF
EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM
DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND
POSSIBLY DEATH. SIGNS AND SYMPTOMS OF OVEREXPOSURE: HEADACHE,
DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATI ONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR
BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:CARBON BLACK: GROUP 2B, IARC MONOGRAPHS
VOLUME 65, PAGE 247, 1996. LUNGS.
Effects of Overexposure:HEALTH HAZARDS: CHRONIC: PROLONGED OVEREXPOSURE
TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER,
URINARY, BLOOD-FORMING, CARDIOVASCULAR, AND REPRODUCTIVE SYSTEMS.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO
SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. CANCER
HAZARD. CONTAINS CARBON BLACK WHICH IS LISTED AS A LUNG CARCINOGEN
. CONTAINS TOLUENE WHIC H APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS LIST. SEEK CONSULTATION FROM APPROPRIATE
HEALTH PROFESSIONAL CONCERNING SAFE HANDLING AND EXPOSURE
INFORMATION .
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. E YES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: SEEK MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:<-17.8C, 0.F
Lower Limits:1.0%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRES SURE BUILD-UP AND POSSIBLE AUTOIGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:EXTREMELY FLAM. FLASH POINT <21F. CLSD
CONTRS MAY EXPLODE (DUE TO PRESS BUILD-UP) WHEN EXPOS TO EXTREME
HEAT. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. APPLICATN
TO HOT SURFS REQUIRES SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO
DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT.
OBTAIN MED ATTN.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP
& SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE COATINGS MAY CONTAIN
MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED AS DUST IN INGS
SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING
SANDING/ABRADING OF DRIED FILM. NFPA CODE 30B - LEVEL 3 AEROSOLS.
Other Precautions:CONTENTS ARE EXTREMELY FLAM. KEEP AWAY FROM HEAT,
SPKS, & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLO.
DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENTILATED; DO NOT
SMOKE; EXTING ALL F LAMES, PILOT LIGHTS, & HEATERS; TURN OFF
STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF IGN IT.
(SUP DAT)

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION.
WHEN SANDING OR ABRADIN G THE DRIED FILM, WEAR A DUST/MIST
RESPIRATOR APPROVED BY NIOSH FOR PROTECTION AGAINST NON-VOLATILES
MATERIALS IN INGREDIENTS SECTION.
Ventilation:LOC EXHAUST PREFERABLE. GEN EXHAUST ACCEPTABLE IF EXPOS IS
MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. REFER TO OSHA
STANDARDS 1910.94, 1910.107, 1910.108.
Protective Gloves:FOR LONG OR REPEATED CONTACT, WEAR CHEMICAL RESISTANT
GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
OTHER PREC: CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROC.
CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F.
HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER, & OTHER HEAT SO
URCES COULD CAUSE CONTR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT
OF REACH OF CHILDREN. (OTHER INFO)

Boiling Pt:<-17.8C, 0.F
B.P. Text:<0F - 395F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER RCRA (40 CFR 261). WASTE MUST BE TESTED FOR
IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE
NUMBERS. DO NOT INCINERATE. DEPRESSUR IZE CONTAINER. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING
POLLUTIO N.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:TOLUENE AND 1-BUTANOL ARE SUBJECT TO THE
REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT (SARA) SECTION 323, 40 CFR 372.65 C.
Federal Regulatory Information:ALL CHEMICALS IN THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS A
CHEMICAL/S KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.